No.

Gas Phase Reactions

A*

β (-)

Ea (cal/mol)

Ref.

1.

H + H + M = H2 + M

1.00 × 1018

−1.0

0.0

[15]

H2 Enhanced by 2.0

2.

H + H + H2 = H2 + H2

9.20 × 1016

−0.6

0.0

[15]

3.

CH3 + CH3 (+M) = C2H6 (+M)

9.22 × 1016

−1.174

636.0

[16]

Low pressure limit: 1.14 × 1036  –5.246  1705.0

TROE centering: 0.405  1120.0  69.6  1.0 × 1015

H2 Enhanced by 2.0

4.

CH3 + H (+M) = CH4 (+M)

2.14 × 1015

–0.4

0.0

[17]

Low pressure limit: 3.31 × 1030  –4.0  2108.0

TROE centering: 0.0  1.00 × 10–15  1.0 × 10–15  40

H2 Enhanced by 2.0

5.

CH4 + H = CH3 + H2

2.20 × 104

3.0

8750.0

[18]

6.

CH3 + H = CH2 + H2

9.00 × 1013

0.0

15100.0

[18]

7.

CH3 + M = CH + H2 + M

6.90 × 1014

0.0

82469.0

[19]

8.

CH3 + M = CH2 + H + M

1.90 × 1016

0.0

91411.0

[19]

9.

CH2 + H = CH + H2

1.00 × 1018

–1.56

0.0

[18]

10.

CH2 + CH3 = C2H4 + H

4.00 × 1013

0.0

0.0

[18]

11.

CH2 + CH2 = C2H2 + H + H

4.00 × 1013

0.0

0.0

[18]

12.

CH2(S) + M = CH2 + M

1.00 × 1013

0.0

0.0

[18]

H2 Enhanced by 12.0

C2H2 Enhanced by 4.0

13.

CH2(S) + CH4 = CH3 + CH3

4.00 × 1013

0.0

0.0

[18]

14.

CH2(S) + C2H6 = CH3 + C2H5

1.20 × 1014

0.0

0.0

[18]

15.

CH2(S) + H2 = CH3 + H

7.00 × 1013

0.0

0.0

[18]

16.

CH2(S) + H = CH + H2

3.00 × 1013

0.0

0.0

[18]

17.

CH2(S) + CH3 = C2H4 + H

2.00 × 1013

0.0

0.0

[18]

18.

CH + H = C + H2

1.50 × 1014

0.0

0.0

[18]

18.

CH + CH2 = C2H2 + H

4.00 × 1013

0.0

0.0

[18]

20.

CH + CH3 = C2H3 + H

3.00 × 1013

0.0

0.0

[18]

21.

CH + CH4 = C2H4 + H

6.00 × 1013

0.0

0.0

[18]

22.

C + CH3 = C2H2 + H

5.00 × 1013

0.0

0.0

[18]

23.

C + CH2 = C2H + H

5.00 × 1013

0.0

0.0

[18]

24.

C2H6 + CH3 = C2H5 + CH4

5.50 × 10−1

4.0

8300.0

[18]

25.

C2H6 + H = C2H5 + H2

5.40 × 102

3.5

5210.0

[18]

26.

C2H5 + H = C2H4 + H2

1.25 × 1014

0.0

8000.0

[15]

27.

C2H5 + H = CH3 + CH3

3.00 × 1013

0.0

0.0

[20]

28.

C2H5 + H = C2H6

1.00 × 1014

0.0

0.0

[15]

29.

C2H4 + H = C2H3 + H2

3.36 × 10−7

6.0

1692.0

[21]

30.

C2H4 + CH3 = C2H3 + CH4

6.62

3.7

9500.0

[15]

31.

C2H4 + H (+M) = C2H5 (+M)

1.08 × 1012

0.454

1822.0

[22]

Low pressure limit: 1.112 × 1034  –5.0  4448.0

TROE centering: 1.0  1.00 × 10–15  95.0  200.0

H2 Enhanced by 2.0